A Rigid Trimetallic Systems for Enhanced Versatility and Special Qualities of Ligand Substitution and Insertion of Organolanthanide(2)

2014 International Conference on Functional Materials(ICFM 2014)——Here,we report selective transformations of different ligands of mixed methyl/methylidene lanthanide complexes,in which some unusual reactivity trends are revealed,indicating that a suitable multimetallic system had a good chance to reverse the normal chemoselectivity of insertion and ligand substitution of organolanthanide complexes.


关键词: 配体取代反应 催化性能 有机合成 2014 International Conference on Functional Materials(ICFM 2014)

主讲人:Prof. Xigeng Zhou 机构:Fudan University

时长:0:19:15 年代:2014年